Xiong, Wei
Investigation of Charge Dynamics and Molecular Conformations at Interfaces
Investigation of Charge Dynamics and Molecular Conformations at Interfaces
Contact Information
Assistant Professor of Chemistry and Biochemistry
Office: Pacific Hall B100C
Phone: 858-534-0270
Email: w2xiong@ucsd.edu
Web: ultrafast.ucsd.edu
Group: View group members
Office: Pacific Hall B100C
Phone: 858-534-0270
Email: w2xiong@ucsd.edu
Web: ultrafast.ucsd.edu
Group: View group members
Education
2011 Ph.D., University of Wisconsin, Madison
2006 B.S., Peking University
2011 Ph.D., University of Wisconsin, Madison
2006 B.S., Peking University
Appointments
2014 Asst. Professor, UCSD
2011 Postdoc, University of Colorado, Boulder
2014 Asst. Professor, UCSD
2011 Postdoc, University of Colorado, Boulder
Awards and Academic Honors
2020
Sloan Research Fellowship
2019
NSF CAREER Award
2019
ACS JPC&PHYS Lectureship Award
2017
DARPA Director's Fellowship
2016
AFOSR Young Investigator Program Award (YIP)
2015
DARPA Young Faculty Award (YFA)
Research Interests
1. Theoretical results demonstrate that interfacial molecular conformations directly influence charge separation dynamics in polymer blend solar cells. Experimentally, it would be very beneficial to be able to monitor the interaction between interfacial conformations and dynamics. However, since charge separation mostly happens at disordered hidden interfaces in thick samples, it is very challenging to capture such processes using existing spectroscopic techniques. We will develop ultrafast surface sensitive spectroscopy to follow both the charge separation dynamics and interfacial conformation simultaneously.
2. The chemical physics of electrocatalysts is complicated and remain a challenge to study, because it happens right at the interfaces. Understanding the microscopic molecular properties at liquid/solid interfaces will be the key for designing new catalysts for better selectivity and lower overpotential. We are specialized in a new interface sensitive technique, called heterodyne 2D SFG spectroscopy, which are able to follow ultrafast dynamics at interfaces. We are interested in using it to determine molecular structure and dynamics of catalysts at liquid/solid interfaces, and transition dynamics in situ.
3. Many Interfaces of materials are heterogeneous. Thus, it would be powerful to visualize molecular conformations and dynamics without confusions from spatial ensemble averaging. We are interested in developing heterodyne SFG based microscopy to visualize heterogeneous interfaces, including MOFs, host-guest self-assemblies, and sea surface monolayers
2. The chemical physics of electrocatalysts is complicated and remain a challenge to study, because it happens right at the interfaces. Understanding the microscopic molecular properties at liquid/solid interfaces will be the key for designing new catalysts for better selectivity and lower overpotential. We are specialized in a new interface sensitive technique, called heterodyne 2D SFG spectroscopy, which are able to follow ultrafast dynamics at interfaces. We are interested in using it to determine molecular structure and dynamics of catalysts at liquid/solid interfaces, and transition dynamics in situ.
3. Many Interfaces of materials are heterogeneous. Thus, it would be powerful to visualize molecular conformations and dynamics without confusions from spatial ensemble averaging. We are interested in developing heterodyne SFG based microscopy to visualize heterogeneous interfaces, including MOFs, host-guest self-assemblies, and sea surface monolayers
Primary Research Area
Physical/Analytical Chemistry
Physical/Analytical Chemistry
Interdisciplinary interests
Materials
Atmospheric and Environmental
Atmospheric and Environmental
Image Gallery
HD SFG Microscopy
CO2 surface catalysts probed by HD 2D SFG
HD SFG Microscopy
CO2 surface catalysts probed by HD 2D SFG
Selected Publications
- Li Y,Shrestha M,Luo M,Sit I,Song M,Grassian VH,Xiong W "Salting Up of Proteins at the Air/Water Interface.", Langmuir, 2019, Vol. 35, Issue 43, 13815-13820 [View Abstract]
- Nadler KA,Kim P,Huang DL,Xiong W,Continetti RE "Water diffusion measurements of single charged aerosols using H2O/D2O isotope exchange and Raman spectroscopy in an electrodynamic balance.", Phys Chem Chem Phys, 2019, Vol. 21, Issue 27, 15062-15071 [View Abstract]
- Porter TM,Wang J,Li Y,Xiang B,Salsman C,Miller JS,Xiong W,Kubiak CP "Direct observation of the intermediate in an ultrafast isomerization.", Chem Sci, 2019, Vol. 10, Issue 1, 113-117 [View Abstract]
- Wang H,Chen W,Wagner JC,Xiong W "Local Ordering of Lattice Self-Assembled SDS@2β-CD Materials and Adsorbed Water Revealed by Vibrational Sum Frequency Generation Microscope.", J Phys Chem B, 2019, Vol. 123, Issue 29, 6212-6221 [View Abstract]
- Xiang B,Ribeiro RF,Li Y,Dunkelberger AD,Simpkins BB,Yuen-Zhou J,Xiong W "Manipulating optical nonlinearities of molecular polaritons by delocalization.", Sci Adv, 2019, Vol. 5, Issue 9, eaax5196 [View Abstract]
- F Ribeiro R,Dunkelberger AD,Xiang B,Xiong W,Simpkins BS,Owrutsky JC,Yuen-Zhou J "Theory for Nonlinear Spectroscopy of Vibrational Polaritons.", J Phys Chem Lett, 2018, Vol. 9, Issue 13, 3766-3771 [View Abstract]
- Lauren E.Buchanan, WeiXiong "Two-Dimensional Infrared (2D IR) Spectroscopy", Encyclopedia of Modern Optics (Second Edition), 2018, Vol. 2, 164-183 [View Abstract]
- Shrestha M,Luo M,Li Y,Xiang B,Xiong W,Grassian VH "Let there be light: stability of palmitic acid monolayers at the air/salt water interface in the presence and absence of simulated solar light and a photosensitizer.", Chem Sci, 2018, Vol. 9, Issue 26, 5716-5723 [View Abstract]
- Xiang B,Ribeiro RF,Dunkelberger AD,Wang J,Li Y,Simpkins BS,Owrutsky JC,Yuen-Zhou J,Xiong W "Two-dimensional infrared spectroscopy of vibrational polaritons.", Proc Natl Acad Sci U S A, 2018, Vol. 115, Issue 19, 4845-4850 [View Abstract]
- Haoyuan Wang, Tian Gao, and Wei Xiong "Self-Phase-Stabilized Heterodyne Vibrational Sum Frequency Generation Microscopy", ACS Photonics, 2017, Vol. 4, Issue 7, 1839 [View Abstract]
- Xiang B,Li Y,Pham CH,Paesani F,Xiong W "Ultrafast direct electron transfer at organic semiconductor and metal interfaces.", Sci Adv, 2017, Vol. 3, Issue 11, e1701508 [View Abstract]
- Ellis JL,Hickstein DD,Xiong W,Dollar F,Palm BB,Keister KE,Dorney KM,Ding C,Fan T,Wilker MB,Schnitzenbaumer KJ,Dukovic G,Jimenez JL,Kapteyn HC,Murnane MM "Materials Properties and Solvated Electron Dynamics of Isolated Nanoparticles and Nanodroplets Probed with Ultrafast Extreme Ultraviolet Beams.", J Phys Chem Lett, 2016, Vol. 7, Issue 4, 609-15 [View Abstract]
- Yingmin Li, Jiaxi Wang, Melissa Clark, Clifford P. Kubiak, Wei Xiong "Characterizing interstate vibrational coherent dynamics of surface adsorbed catalysts by fourth-order 3D SFG spectroscopy", Chem. Phy. Lett., 2016, Vol. 650, Issue 16, 1 [View Abstract]
- Zhiguo Li, Jiaxi Wang, Yingmin Li, and Wei Xiong "Solving the “Magic Angle” Challenge in Determining Molecular Orientation Heterogeneity at Interfaces", JPCC, 2016, Vol. 120, Issue 36, 20239 [View Abstract]
- Jennifer L Ellis, Daniel D Hickstein, Kyle J Schnitzenbaumer, Molly B Wilker, Brett B Palm, Jose L Jimenez, Gordana Dukovic, Henry C Kapteyn, Margaret M Murnane, Wei Xiong "Solvents effects on charge transfer from quantum dots", JACS, 2015, Vol. 137, Issue 11, 3759-3762 [View Abstract]
- Jiaxi Wang, Melissa L. Clark, Yingmin Li, Camille L. Kaslan, Clifford P. Kubiak, and Wei Xiong "Short-Range Catalyst–Surface Interactions Revealed by Heterodyne Two-Dimensional Sum Frequency Generation Spectroscopy", JPCL, 2015, Vol. 6, 4204-4209 [View Abstract]
- Yingmin Li, Jiaxi Wang, and Wei Xiong "Probing Electronic Structures of Organic Semiconductors at Buried Interfaces by Electronic Sum Frequency Generation Spectroscopy", JPCC, 2015, Vol. 119, Issue 50, 28083 [View Abstract]
- Ding C, Xiong W, Fan T, Hickstein DD, Popmintchev T, Zhang X, Walls M, Murnane MM, Kapteyn HC, "High flux coherent super-continuum soft X-ray source driven by a single-stage, 10mJ, Ti:sapphire amplifier-pumped OPA.", Opt Express, 2014, Vol. 22, Issue 5, 6194-202 [View Abstract]
- Hickstein DD, Dollar F, Ellis JL, Schnitzenbaumer KJ, Keister KE, Petrov GM, Ding C, Palm BB, Gaffney JA, Foord ME, Libby SB, Dukovic G, Jimenez JL, Kapteyn HC, Murnane MM, Xiong W. "Mapping nanoscale absorption of femtosecond laser pulses using plasma explosion imaging.", ACS Nano, 2014, Vol. 8, Issue 9, 8810-8818 [View Abstract]
- Hickstein DD, Dollar F, Gaffney JA, Foord ME, Petrov GM, Palm BB, Keister KE, Ellis JL, Ding C, Libby SB, Jimenez JL, Kapteyn HC, Murnane MM, Xiong W, "Observation and control of shock waves in individual nanoplasmas.", Phys Rev Lett, 2014, Vol. 112, Issue 11, 115004 [View Abstract]
- Xiong W, Hickstein DD, Schnitzenbaumer KJ, Ellis JL, Palm BB, Keister KE, Ding C, Miaja-Avila L, Dukovic G, Jimenez JL, Murnane MM, Kapteyn HC, "Photoelectron spectroscopy of CdSe nanocrystals in the gas phase: a direct measure of the evanescent electron wave function of quantum dots.", Nano Lett, 2013, Vol. 13, Issue 6, 2924-30 [View Abstract]
- Laaser JE, Xiong W, Zanni MT, "Time-domain SFG spectroscopy using mid-IR pulse shaping: practical and intrinsic advantages.", J Phys Chem B, 2011, Vol. 115, Issue 11, 2536-46 [View Abstract]
- Xiong W, Laaser JE, Mehlenbacher RD, Zanni MT, "Adding a dimension to the infrared spectra of interfaces using heterodyne detected 2D sum-frequency generation (HD 2D SFG) spectroscopy.", Proc Natl Acad Sci U S A, 2011, Vol. 108, Issue 52, 20902-7 [View Abstract]
- Woys AM, Lin YS, Reddy AS, Xiong W, de Pablo JJ, Skinner JL, Zanni MT, "2D IR line shapes probe ovispirin peptide conformation and depth in lipid bilayers.", J Am Chem Soc, 2010, Vol. 132, Issue 8, 2832-8 [View Abstract]
- Xiong W, Laaser JE, Paoprasert P, Franking RA, Hamers RJ, Gopalan P, Zanni MT, "Transient 2D IR spectroscopy of charge injection in dye-sensitized nanocrystalline thin films.", J Am Chem Soc, 2009, Vol. 131, Issue 50, 18040-1 [View Abstract]
- Xiong W, Zanni MT, "Signal enhancement and background cancellation in collinear two-dimensional spectroscopies.", Opt Lett, 2008, Vol. 33, Issue 12, 1371-3 [View Abstract]