Combustion of Magnesium in Carbon Dioxide
Materials
2 blocks of Dry Ice with hollows drilled out about 0.5 cm deep
Small bottle of Magnesium Turnings (about 10g)
Propane Torch
Thermal Gloves
Crucible Tongs
Gloves and Goggles
Procedure
- There are two dry ice blocks with identical cavities in them.
- Fill one cavity about half full with magnesium filings.
- Holding the covering block with one hand, light the filings with the torch.
- Cover burning magnesium with the other block, making sure the cavities line up.
- Dim lights.
- After the Mg stops burning, drop the residue out and break it open.
- The class usually wants an instant replay
Reactions
2Mg + CO2 --> 2MgO + C
Standard heat of reaction is -809kJ.
The black residue is a mixture of carbon and magnesium nitride, Mg3N2.
Waste Management
Once cool, the carbon residue can be thrown in the trash.
Note: Do this in a well ventilated room - I have set the fire alarm off with the haze generated from this demonstration.